A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors.
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Authors
Abstract
We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred secondary building unit (SBU). The presented study indicates that controlling the acid-base relationship between reagents is key to mechanochemical synthesis of IRMOFs, revealing a pre-assembled oxo-zinc amidate cluster as an efficient precursor for IRMOF mechanosynthesis.
Description
Keywords
0306 Physical Chemistry (incl. Structural)
Journal Title
Chem Commun (Camb)
Conference Name
Journal ISSN
1359-7345
1364-548X
1364-548X
Volume Title
51
Publisher
Royal Society of Chemistry (RSC)
Publisher DOI
Sponsorship
The authors would like to acknowledge the project operated within the Foundation for Polish Science Team Programme co-financed by the EU ‘‘European Regional Development Fund’’ TEAM/2011–7/8, and the European Union in the framework of Regional Development Fund through the Joint UW and WUT International PhD Program of Foundation for Polish Science – “Towards Advanced Functional Materials and Novel Devices” (MPD/2010/4) (D.P.) for financial support.